Thiourea is an organic compound of carbon, nitrogen, sulfur and hydrogen, with the formula CSN2H4 or (NH2)2CS.It is similar to urea, except that the oxygen atom is replaced by a sulfur atom. The properties of urea and thiourea differ significantly because of the relative electronegativities of sulfur and oxygen.Thiourea is a versatile reagent in organic synthesis.
An efficient and simple thiourea-mediated regioselective synthesis of symmetrical and unsymmetrical diversifiedthioethers is reported. The regioselective reaction avoids byproduct formation and offers simplified methodology, widerapplicability, and easy workability and an environmentally friendly approach toward symmetrical and unsymmetrical thioethers.The mechanism of formation of thiols and.
Thiourea as an inexpensive and easy-to-handle sulfur atom transfer reagent, was used extensively as well, mainly for the synthesis of inorganic metal sulfides (40,41,42), organic thioethers (43,44,45,46,47), and thioesters (48,49). As far as we known, a similar reaction using thiourea and aldehydes to prepare thioamides has not yet been introduced.
Literature review reveals a handsome number of reports pointing towards synthesis and characterization of metal complexes stabilized by thiourea derivatives particularly Zn, Cd and Hg (,, ). These metals are electron rich and their complexes with thiourea have outstanding non-linear optical properties (,, ).
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